This sounds like a DHCP server configuration issue or an issue with your DNS server. Wireless Configuration: What mode do you have selected under Addressing and Traffic? (NAT mode, Bridge mode, L3 Roaming, L3 Roaming + Concentrator, or VPN) (Wireless > Access control) Are you using VLAN Tagging? If so, are both SSIDs associated to the same VLAN? (Wireless > Access control) Do you have any firewall/traffic shaping rules enforced on these subnets? Bandwidth limits defined? (Wireless > Firewall & Traffic Shaping) What kind of devices connect to these SSIDs? How many? Do you have any Network-wide group policies assigned by device type? (Wireless > Access control) Servers: Have you checked the DNS Server scope option on the DHCP server for the subnet(s) associated with the 2 SSIDs that are experiencing issues? Have you checked the resource utilization on your DNS server(s) to make sure that your CPU and Memory are not being heavily utilized? (this was a culprit to a similar issue I experienced not too long ago...)
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