Hi @RichJ so I wasn't sure if this was one MR33 AP or multiple APs? If multiple, they are all doing this behavior at the same time? And if just a single AP, it's happening at those same times, night after night? Has the MS220 switch been rebooted? I'd also consider that to rule out a switch issue. Review your change log and/or recent firmware updates just to see if anything lines up with the onset of this problem.
Also, you mention the blue LED, which indicates at least 1 client is actively connected on at least 1 SSID. Is the wireless network usable for the clients during that time? If yes, perhaps it's a Dashboard connectivity related. If the wireless is unusable for clients from 20:30 to 06:00 then it's more than just Dashboard connectivity. Regardless it needs to be investigated. Is there a Meraki Support case opened for investigation? They can check if and how the MR33(s) are checking into Dashboard.