PPPoE is strictly point to point. While you can run it through a switch it only allows one client (aka MX) to connect.
You will need a second extra circuit to make this work. It could be another PPPoE circuit. It could be a USB 4G stick plugged into the warm spare. It could be a 4G hotspot plugged in via Ethernet to WAN2 on both MX's.
Note that a 4G connection running as a backup uses about 100MB per month in monitoring traffic.