Hi Coen,
These were the things to check:
1. Do you have a Layer 7 Policy on the firewall rule which contains DENY Social Web & Photo Sharing? If none, proceed to number 3.
2. If yes, erase that firewall rule or allow the Layer 7 traffic. We'll be blocking the traffic by using the content filtering.
3. On the Content Filtering, blocked category websites should have the Social Networking.
4. On the White listed URL Section, I have attached a screenshot for the domains i white listed to allow the Workplace Facebook but blocked the Facebook itself.
Then it's done.
Please do note that i didn't used wildcard to whitelist the URL's. For the scontent domain, it is always changing. Please check your event logs for this one.
I hope this guide helps.