You can configure your primary NPS RADIUS server to proxy/forward requests to the secondary NPS server.
https://learn.microsoft.com/en-us/windows-server/networking/technologies/nps/nps-top
This is an advanced RADIUS concept. I don't recommend you do it.
Taking a step back and looking at the wider requirement, I would change over to using Cisco AnyConnect and have it SAML authentication directly against Entra ID. Then you don't need RADIUS servers, and it will use whatever MFA you have Entra ID configured to use.
You could keep your existing users on the Windows client VPN (I believe that is what you mean), and then install AnyConnect and migrate the users across slowly.
You will need to buy AnyConnect licences, but they are not expensive.
https://documentation.meraki.com/MX/Client_VPN/AnyConnect_on_the_MX_Appliance/AnyConnect_Azure_AD_SA...